To my knowledge, the term relaxation is used to indicate that a constraint (or a group of constraints) is removed from the model, rendering a model that is more loose, less constrained.
In the context of Lagrangian relaxation, a constraint (or group of constraints) is removed from the model, and added to the objective function with a coefficient (or more precisely, the right hand term minus the left hand term). The idea is that if this additional term has value $0$ in the objective function, the constraint is satisfied.
The term linear relaxation is also very common. It appears when integrity constraints are removed from the model (variables that have to be discrete can be continuous).
For the shortest path problem, it is the same : one of the constraint that models the shortest path is removed, in some sense. You can model the shortest path problem from $u$ to $v$ in a graph $G=(V,E)$ as follows :
$$
\max \; d_v
$$
subject to
\begin{align}
d_j &\le d_i + c_{ij} \quad \forall (i,j) \in E \\
d_u &= 0
\end{align}
In essence, the shortest path from $u$ to $v$, $d_v$, is the largest value that minimizes $d_i+c_{iv}$ for all predecessors $i$ of $v$. The constraint $d_j \le d_i +c_{ij}$ is only active when $d_i$ is the shortest path length to node $i$. When it is not the case, the constraint is inactive and you can relax it from the model. This is what is done dynamically (and not through linear programming) in the slides of the link you have posted.
There is a nice physical interpretation of this. Imagine you have some sort of web with extremities $u$ and $v$. If you stretch $u$ from $v$ as much as possible, the tightest string from $u$ to $v$ is the shortest path from $u$ to $v$. All other strings from $u$ to $v$ are loose or wavy, hence the term "relaxed." This is illustrated in the image below (from Wikipedia) :
Finding the shortest path in a graph using optimal substructure; a
straight line indicates a single edge; a wavy line indicates a
shortest path between the two vertices it connects (among other paths,
not shown, sharing the same two vertices); the bold line is the
overall shortest path from start to goal.

For this particular graph, if nodes are named $a$, $b$, $c$ from top to bottom, the above linear formulation yields :
$$
\max \; d_{goal}
$$
subject to
\begin{align}
d_a &\le d_{start}+5 \\
d_b &\le d_{start}+2 \\
d_c &\le d_{start}+11 \\
d_{goal} &\le d_a + 20 \\
d_{goal} &\le d_b + 25 \\
d_{goal} &\le d_c + 17 \\
d_{start} &= 0 \\
\end{align}
Which can easily be simplified to
\begin{align}
d_a &\le 5 \\
d_b &\le 2 \\
d_c &\le 11 \\
d_{goal} &\le d_a + 20 \\
d_{goal} &\le d_b + 25 \\
d_{goal} &\le d_c + 17
\end{align}
It is easy to see that the last two constraints could be removed from the model : they can be relaxed. Physically, if you stretch the graph from $start$ to $goal$, edges $(b,goal)$ and $(c,goal)$ end up wavy/loose/"relaxed".